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I figured it out a about 18 months ago. Why did my Les Paul Traditional clean up so nicely but stayed at nearly the same volume all the way down to 3 or so? My other guitars with the expensive replacement pots were almost on-off switches (between 8-10) in comparison.
Eventually, I found out that Gibson had put linear taper pots on the volumes. I'm gradually switching all my guitars over - SO much better for what I want.
The only disadvantage is that you will get a bit more treble loss at low volume settings because the effective load resistance of the pot has decreased.
"Take these three items, some WD-40, a vise grip, and a roll of duct tape. Any man worth his salt can fix almost any problem with this stuff alone." - Walt Kowalski
"Only two things are infinite - the universe, and human stupidity. And I'm not sure about the universe." - Albert Einstein
I haven't found one audio taper I like yet and I'm not trying anymore out
(formerly customkits)
http://www.maplin.co.uk/c/components/resistors#Category:Metal Film Resistors&sort=price-asc&page=0&productsPerPage=showAll
You only need the lowest power rating - their 0.6W metal film ones are ideal. 9p each by the look of it!
"Take these three items, some WD-40, a vise grip, and a roll of duct tape. Any man worth his salt can fix almost any problem with this stuff alone." - Walt Kowalski
"Only two things are infinite - the universe, and human stupidity. And I'm not sure about the universe." - Albert Einstein
A log pot works (in most sound situations) as it directly controls the volume of output - and your ears respond in a logarithmic like fashion, so a log pot is what you want for that role - so it appears to act in a "linear" fashion. The two logs cancel out if you will.
However, what's going on here is quite different. If you were playing clean and just after volume, a log is what you'd want. But what's actually hapenning is your using it as a distortion control for the amp.
Once you're out of the clean part of the performance, the output wave form in a guitar amp won't get any taller, but it will become more distorted (and therefore sound louder and add more overtones). SInce this distortion is proportional to the input signal - that is, it has a linear relationship - a log pot won't suit well, since all the change is at one end (by design) and it will feel (as you describe) like a switch. So a linear pot will work better.
In other words - clean volmue control - log; distortion "volume" control - linear.