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The adjustable function on my Antex iron broke within a fortnight, the same crappy design as your Amazon one. Still heats up though so I use it anyway.
There's a lot of digitally adjustable ones available too from places like Maplin. I've heard they're good.
https://www.maplin.co.uk/p/60w-mains-lcd-solder-station-a55kj
Leaded solder flows best but you don't want to be breathing it in. Unleaded solder is ok. I use it with added silver, which is more expensive but works pretty well.
https://www.maplin.co.uk/p/lead-free-silver-solder-roll-100g-n32ar
Use one of these to clean the tip after each application of solder, and not that damp sponge thingy that comes with the iron:
https://www.amazon.co.uk/gp/product/B071CG44HT/ref=oh_aui_detailpage_o08_s00?ie=UTF8&psc=1
I'm back to doing more soldering for kits etc so am about to bite the bullet and buy a decent Hakko unit. Nothing wrong with a cheapo though, for as long as they last!
Also chips are "Plant-based" no matter how you cook them.
the bits and pieces (solder pump, wire clippers) you can pick up for pennies on ebay or hardware store if decide you need them. most of those bits you probably have in some form. (the ones with that kit look a bit cheap tbh).
you can get decent enough am-tech mini pliers and clippers for a pound a time that are way better. get long nose and standard pliars and small side clippers. tube of solder is £1.
as for tips, you only need a pencil tip and a chisel tip at most. pencil is all i use (it comes with). replacement coated tips for these are easy to find, only cost £1 on ebay and last for quite a while.
i got the maplin version of this one four years ago and it's stil going strong. had two tip replacements in that time. never overheated. good range of temperatures. perfect starter.
and do buy some safety glasses. if a spitty bit of solder-flux throws something up it can save your sight. well worth the £1.
http://www.ebay.co.uk/itm/58W-Moss-Variable-Temperature-control-Soldering-Station-Iron-Electronic-Stand/272697904621?epid=933177164&hash=item3f7e0fcded:g:WaQAAOSwIQdZMMgC