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Applying black stain on top of white stain shouldn't be a major issue - eg there are various Crimson YT vids showing how they build up sunburst effects by using one colour on top of another. However, the more white you remove, the more black the final colour will be (as opposed to grey!).
*BUT*, I'm guessing you're going to need to remove all of the finishing oil otherwise that'll stop the black getting into the wood. That might well be the trickier bit, depending on how far it penetrated into the wood, through the original white.
Trial and error. Every piece of wood is different. The way that you applied the existing finish is likely different to the way that someone else would have done it.
Sand back until it looks and feels clean. Try some of the new colour. If the result is as you want, carry on staining. If the result is not as you want (eg uneven or blotchy), then sand some more.