My understanding is that in an amp context, "gain" refers to preamp signal strength and "volume" refers to the power amp signal strength.
So, in a pedal that comes before the pre-amp, if gain and volume were to both control signal strength, they would both be doing the same job since they're both controlling the signal strength going into that pre-amp.
Is it more correct to say that only the volume knob controls the signal strength whilst the gain knob actually doing something different, eg adding synthetic distortion? Or are they both controlling the signal strength in different ways?
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Bandcamp
Spotify, Apple et al
This should be a very useful read for you
http://justinguitarcommunity.com/index.php?topic=33317.0
It's a little more complicated in reality, but that's the essence of it.
When used on guitar amps it's normally a volume control in the preamp section which controls how much preamp distortion you get.
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