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Knocking massively increases engine ware so if you have a high output engine for its size use 98 octane.
Also is the type of driving the same? Ie all motorway, all town, 50/50 etc.
Much more powerful fuel used to be developed by race teams until they regulated fuel use and only allowed stuff buy-able at the pump. (and indeed much lower octane fuel is still common in the US to run low power V8s). The fuel used by drag racers is insane stuff (Nitromethane). 10,000 bhp from a 4 lite engine with that stuff.
Ringleader of the Cambridge cartel, pedal champ and king of the dirt boxes (down to 21)
Now who do you think will have put the most research and development time into which additives work the very best, Shell, or Asda? Asda will spend as little as possible on ingredients, and the adding of the additives to keep final price rock bottom, whereas shell will spend a bit more on the chemicals and such added, and keeping quality high and consistent.
These additives will affect MPG, how well the engine runs, lubricating/cleaning from the inside out etc. If you go to a garage with a blocked fuel filter the first thing they will as is have you been buying supermarket fuel, they generally don't add the additives that help to break up any impurities so they are small enough to be combusted and expelled through the exhaust.
These additives won't make the world of difference, possibly not enough to justify the extra 2p per litre, possibly enough to more than justify the difference, but your milage may vary. (laughs at himself for brilliant pun)
My new car is a 2.2D Mazda 3, and I've been using Esso diesel and getting between 45-50 mpg. Since this thread came up I have filled with the Esso Synergy Supreme+ Diesel and even after just quarter of a tank my mpg is sitting at 58! That has been more town driving than normal as I am on holiday (I do a lot of miles in my job, mostly long A road/motorway journeys) so I expect that mpg to increase when work duties recommence.
Synergy Ultimate+ diesel was £1.27 per litre whereas standard Esso diesel was £1.14. Not sure that 13p per litre extra is cost effective as yet but the performance difference is noticeable. Smoother and slightly quieter too.
I'll keep an eye out for Shell garages when I'm on the road and try their V Power out. None round my way.
Saying that I've never worked on a shell or Esso refinery so they might do things differently, but mainly it's refined to an agreed spec and shipped overseas or sold to supermarkets in an as raw state as possible.
For years the USA was buying the majority of UK production primarily for east cost distribution but that has slowed of late, I mention that as they definitely did not spec anything other than basic low octane unleaded ( with a healthy dose of benzene).
In fact, when lab tested there was no difference between a supermarket brand and a standard BP fuel of the time.
From what I have been told, the only fuels that are in any way 'different' are the premium ones - and that is due to additives etc that are put into the mix way before they get to bulk storage - much like @grungebob says above.
What is interesting in this thread are real-world examples of where premium fuels *are* living up to the hype. I'm trying Shell premium diseasal in the super-mileage Golf this week... the mpg figures on the display seem to be up a bit compared to normal but I'm not counting any chickens until the fuel is used up and I can do a proper mpg calculation.
After a cheap supermarket opened near me, I tested it over an average thousand miles on both types, twice for each, and the difference was consistent - the supermarket gave worse fuel economy by a noticeable amount (about 3%).
What kind of lab test? A full chemical analysis showing all trace compounds, or a burn test to show energy content?
"Take these three items, some WD-40, a vise grip, and a roll of duct tape. Any man worth his salt can fix almost any problem with this stuff alone." - Walt Kowalski
"Only two things are infinite - the universe, and human stupidity. And I'm not sure about the universe." - Albert Einstein